21 March 2025
Corundum is a mineral species that encompasses two of the most coveted varieties in the gemstone market: sapphires and rubies. While sapphires can be found in a spectrum of colours, rubies are specifically defined as red corundum, exhibiting a distinct hue due to the presence of chromium. One of the most prevalent methods for enhancing these gemstones is heat treatment, a process that significantly modifies their physical and optical properties.
Table of ContentsWhat Is Corundum and Why Is It Heat Treated?How Heat Treatment Changes Ruby and SapphireHeat-Expanded Crystals and Fracture Halos in CorundumOther Signs of Heat TreatmentHow Gemmologists Test for Heat TreatmentWhy Corundum Treatment Disclosure Matters
What Is Corundum and Why Is It Heat Treated?
The mineral is crystalline aluminium oxide (Al2O3). In its purest form it is colourless, but trace elements such as chromium, iron and titanium give rise to the reds of ruby and the blues, yellows and pinks of sapphire. Ranking 9 on the Mohs scale, it is second only to diamond in hardness.
Much of the rough mined today is pale, cloudy or unevenly coloured. Heating can dissolve silk, improve transparency and deepen or lighten colour, which is why the vast majority of commercial ruby and sapphire on the market has been heat treated. The treatment is stable and widely accepted, but it must always be disclosed.
How Heat Treatment Changes Ruby and Sapphire
Heat treatment involves exposing corundum to elevated temperatures, typically ranging from 1,200°C to 1,600°C, resulting in notable changes within the crystal structure. Less common treatments can occur at temperatures as low as 800°C and as high as 1,700°C.
This process can lead to the formation of heat-expanded crystals, which serve as critical indicators of whether a stone has undergone enhancement. Furthermore, inclusions such as silk (rutile needles), fingerprints and colour zoning can be diminished or altered during heat treatment, potentially transforming the stone’s overall appearance.
Heat-Expanded Crystals and Fracture Halos in Corundum
During the heat treatment process, the crystal lattice of corundum expands, influencing the visibility and nature of internal inclusions. Mineral inclusions, such as other crystal fragments, expand at a different rate to the host and may develop distinctive fracture halos around them due to the thermal stress induced by the heat, as illustrated in the accompanying images.
These halos can resemble an explosion effect, with the surrounding material appearing fractured and radiating away from the inclusion. The presence of heat-expanded crystals, along with these characteristic fracture halos, can often be observed under a microscope, providing clear evidence of the stone’s treatment history.
While such fracture halos are strong indicators of heat treatment, it is important to note that they can also occur in untreated stones, albeit rarely. Careful examination of all inclusions is therefore essential before a conclusion is reached.
Other Signs of Heat Treatment
Heat-expanded crystals are rarely the only clue. When examining a ruby or sapphire, a gemmologist will also look for the following features:
Altered silk: rutile needles that appear dotted, broken or partially dissolved rather than long and continuous.
Discoid fractures: flat, disc-like tension fractures surrounding small included crystals.
Chalky fluorescence: a chalky blue or green glow under short-wave ultraviolet light, often seen in heated blue sapphire.
Colour zoning: diffuse or blurred colour banding where the original sharp zoning has been softened by heat.
Surface features: pitted or glassy facet junctions where the stone was heated after cutting.
How Gemmologists Test for Heat Treatment
Gemmologists employ advanced techniques, such as gemmological microscopy and testing on specialised equipment including Fourier transform infrared spectroscopy (FTIR), to investigate these inclusions and determine the authenticity and treatment status of sapphires and rubies. A skilled gemmologist should be capable of identifying fracture halos using a loupe or microscope.
Heat treatment should also be distinguished from other enhancements. Lead glass filling in ruby and the gas bubbles found in synthetic ruby present very differently under magnification, and each carries very different implications for value. Organisations such as the Gemological Institute of America (GIA) publish detailed research on the inclusions associated with heated stones.
Why Corundum Treatment Disclosure Matters
Recognising heat-expanded crystals and their associated fracture halos is crucial for both assessing gem quality and educating consumers. An unheated ruby or sapphire of fine colour can command a significant premium over a heated stone of similar appearance, so the treatment status directly affects what a buyer should expect to pay.
At E.D.R – European Diamond & Gemstone Reports in London, every ruby and sapphire we examine is checked for evidence of heating, and the result is stated clearly on our Loose Gemstones Report. If you own a ruby or sapphire and would like to know whether it has been treated, get in touch with our laboratory.
In conclusion, understanding the effects of heat treatment on corundum, along with the implications of crystal expansions and fracture halos, is essential for all professionals in the gemstone industry. By recognising these characteristics, gemmologists can provide valuable insights into the origins and enhancements of sapphires and rubies, empowering consumers to make informed decisions.